1,1,2,2-Tetra-kis(diisopropyl-amino)diphosphane

Acta Crystallogr Sect E Struct Rep Online. 2009 Aug 22;65(Pt 9):o2214. doi: 10.1107/S1600536809032802.

Abstract

In the title compound, C(24)H(56)N(4)P(2), the distance between the P atoms [2.2988 (8) and 2.3013 (13) Å in the major and minor occupancy components, respectively] is one of the longest reported for uncoordinated diphosphanes. The whole mol-ecule is disordered over two positions with site-occupation factors of 0.6447 (8) and 0.3553 (8). The structure adopts the synperiplanar conformation in the solid state [N-P-P-N torsion angle = 14.7 (5)°].