An inter-molecular dative B←N bond in 5-(4,4,5,5-tetra-methyl-1,3,2-dioxa-borolan-2-yl)-1,3-thia-zole

Acta Crystallogr Sect E Struct Rep Online. 2009 Dec 16;66(Pt 1):o156. doi: 10.1107/S1600536809052775.

Abstract

The title compound, C(9)H(14)BNO(2)S, is in an unusual bend conformation and the B atom of one mol-ecule within the crystal forms an inter-molecular dative bond with the N atom of a neighbouring mol-ecule, an infrequent phenomenon in boronic derivative crystals.