A disposable electrochemical sensor for the determination of indole-3-acetic acid based on poly(safranine T)-reduced graphene oxide nanocomposite

Talanta. 2011 Jul 15;85(1):310-6. doi: 10.1016/j.talanta.2011.03.070. Epub 2011 Apr 5.

Abstract

A disposable electrochemical sensor for the determination of indole-3-acetic acid (IAA) based on nanocomposites of reduced graphene oxide (rGO) and poly(safranine T) (PST) was reported. The sensor was prepared by coating a rGO film on a pre-anodized graphite electrode (AGE) through dipping-drying and electrodepositing a uniform PST layer on the rGO film. Scanning electron microscopic (SEM) and infrared spectroscopic (IR) characterizations indicated that PST-rGO formed a rough and crumpled composite film on AGE, which exhibited high sensitive response for the oxidation of IAA with 147-fold enhancement of the current signal compared with bare AGE. The voltammetric current has a good linear relationship with IAA concentration in the range 1.0×10(-7)-7.0×10(-6)M, with a low detection limit of 5.0×10(-8)M. This sensor has been applied to the determination of IAA in the extract samples of several plant leaves and the recoveries varied in the range of 97.71-103.43%.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Electrochemical Techniques / methods*
  • Electrodes
  • Graphite
  • Indoleacetic Acids / analysis*
  • Limit of Detection
  • Nanocomposites / chemistry*
  • Oxides
  • Phenazines
  • Plant Extracts / chemistry*
  • Plant Growth Regulators / analysis*
  • Plant Leaves
  • Polymers

Substances

  • Indoleacetic Acids
  • Oxides
  • Phenazines
  • Plant Extracts
  • Plant Growth Regulators
  • Polymers
  • indoleacetic acid
  • Graphite
  • safranine T