Topochemical approach to efficiently produce main-chain poly(bile acid)s with high molecular weights

Chem Commun (Camb). 2011 Jul 21;47(27):7728-30. doi: 10.1039/c1cc11445j. Epub 2011 Jun 7.

Abstract

Based on a topochemical approach, a strategy for efficiently producing main-chain poly(bile acid)s in the solid state was developed. This strategy allows for facile and scalable synthesis of main-chain poly(bile acid)s not only with high molecular weights, but also with quantitative conversions and yields.

MeSH terms

  • Alkynes / chemical synthesis
  • Alkynes / chemistry
  • Azides / chemical synthesis
  • Azides / chemistry
  • Bile Acids and Salts / chemical synthesis*
  • Bile Acids and Salts / chemistry
  • Green Chemistry Technology / economics
  • Green Chemistry Technology / methods*
  • Molecular Weight
  • Polymers / chemical synthesis*
  • Polymers / chemistry

Substances

  • Alkynes
  • Azides
  • Bile Acids and Salts
  • Polymers