Abstract
The total synthesis of optically active phenylbutenoid dimers 1, 3, and ent-3 is described. The key step to access optically active cyclohexene rings was achieved by Diels-Alder reaction of chiral acryloyloxazolinone 9 and phenylbetadiene 10.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Benzene Derivatives / chemical synthesis*
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Benzene Derivatives / chemistry
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Benzene Derivatives / pharmacology*
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Butyrates / chemical synthesis*
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Butyrates / chemistry
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Butyrates / pharmacology*
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Cyclohexenes / chemical synthesis*
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Cyclohexenes / chemistry
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Cyclohexenes / pharmacology*
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Female
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Humans
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Molecular Structure
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Stereoisomerism
Substances
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Benzene Derivatives
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Butyrates
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Cyclohexenes