Anomalous x-ray diffraction peak broadening and lattice strains in Zn(1-x)Co(x)O dilute magnetic semiconductors

J Phys Condens Matter. 2009 Feb 18;21(7):075801. doi: 10.1088/0953-8984/21/7/075801. Epub 2009 Jan 23.

Abstract

Nanocrystalline powders of Zn(1-x)Co(x)O synthesized by the coprecipitation technique show anomalous anisotropic broadening for x>0.05. This peak broadening is shown to be not only due to a reduction in the particle size but also due to a significant strain contribution, as confirmed by Williamson-Hall analysis. The presence of grouped Co(2+) ions, revealing the presence of clusters of high spin Co(2+) with antiferromagnetically coupled spins, as indicated by magnetization studies, seems to be responsible for the strain.