Total synthesis of dermostatin A

J Org Chem. 2011 Oct 7;76(19):7641-53. doi: 10.1021/jo2012658. Epub 2011 Sep 15.

Abstract

The concise total synthesis of dermostatin A is described. Highlights include a two-directional application of the asymmetric acetate aldol method developed in our lab, a novel diastereotopic-group-selective acetal isomerization for terminus differentiation, and a selective cross-metathesis reaction between a terminal olefin and a trienal. A study of the scope and viability of similar cross-metathesis reactions is also described. The synthesis is convergent and utilizes fragments of roughly equal complexity.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Chemistry Techniques, Synthetic / methods*
  • Polyenes / chemical synthesis
  • Polyenes / chemistry
  • Polymers / chemistry
  • Stereoisomerism
  • Substrate Specificity

Substances

  • Polyenes
  • Polymers
  • polyol
  • dermostatin A