Communication: probable scenario of the liquid-liquid phase transition of SnI4

J Chem Phys. 2011 Sep 7;135(9):091101. doi: 10.1063/1.3637038.

Abstract

We have shown from in situ synchrotron x-ray diffraction measurements that there are two thermodynamically stable liquid forms of SnI(4), depending on the pressure. Based on the liquid-liquid critical point scenario, our recent measurements suggest that the second critical point, if it exists, may be located in a region close to the point at which the melting curve of the crystalline phase abruptly breaks. This region is, unlike that of water, experimentally accessible with relative ease.