Abstract
This Perspective outlines work in the Crich group on the diastereoselective synthesis of the so-called difficult classes of glycosidic bond: the 2-deoxy-β-glycopyranosides, the β-mannopyranosides, the α-sialosides, the α-glucopyranosides, and the β-arabinofuranosides with an emphasis on the critical interplay between mechanism and methodology development.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Arabinose / analogs & derivatives*
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Arabinose / chemistry
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Chemistry, Organic
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Chemistry, Physical
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Deoxy Sugars / chemistry*
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Glucosides / chemistry*
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Magnetic Resonance Spectroscopy
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Molecular Structure
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Stereoisomerism
Substances
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Deoxy Sugars
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Glucosides
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arabinofuranose
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Arabinose