Surface structure and catalytic properties of MoO3/CeO2 and CuO/MoO3/CeO2

Wujiang Yu; Jie Zhu; Lei Qi; Chuanzhi Sun; Fei Gao; Lin Dong; Yi Chen

doi:10.1016/j.jcis.2011.08.022

Surface structure and catalytic properties of MoO3/CeO2 and CuO/MoO3/CeO2

J Colloid Interface Sci. 2011 Dec 15;364(2):435-42. doi: 10.1016/j.jcis.2011.08.022. Epub 2011 Aug 16.

Authors

Wujiang Yu¹, Jie Zhu, Lei Qi, Chuanzhi Sun, Fei Gao, Lin Dong, Yi Chen

Affiliation

¹ Key Laboratory of Mesoscopic Chemistry of Ministry of Education, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210093, PR China.

PMID: 21930282
DOI: 10.1016/j.jcis.2011.08.022

Abstract

XRD, LRS, TPR and in situ NH(3) adsorption FT-IR were used to investigate the dispersion state of the copper oxide and molybdena species of MoO(3)/CeO(2) and CuO/MoO(3)/CeO(2) catalysts as well as their surface acidity. The results showed that the molybdena monolayer modification promoted the dispersion of CuO due to the formation of new tetrahedral vacancies. Meanwhile, CuO changed the structure of molybdenum species and then influenced the surface acidity of the samples. A detail discussion about the possible model of the surface structure of the catalyst was presented. In addition, combining with the in situ NH(3) adsorption FT-IR, the relationships between the activities for ''NO + NH(3) + O(2)'' reaction and surface acid properties (Brønsted and Lewis acid sites) of the catalysts were discussed.