Supercritical fluid chromatography in research laboratories: design, development and implementation of an efficient generic screening for exploiting this technique in the achiral environment

J Chromatogr A. 2011 Nov 25;1218(47):8551-60. doi: 10.1016/j.chroma.2011.09.029. Epub 2011 Sep 16.

Abstract

A new strategy for exploiting SFC in the achiral arena has been designed, developed and successfully implemented in our Analytical Technologies laboratories, in support of Drug Discovery. The development of a generic analytical SFC/MS screening protocol, following extensive evaluation of different stationary phase, modifier and gradient elution combinations, has enabled fast analytical method development for structurally diverse compounds within both specialised and high-throughput purification environments. Application of this approach into the daily routine has provided data on a large number and a wide variety of reaction mixtures. The results confirm the scope and generality of the strategy with more than 85% of targets being successfully resolved from their impurities.

MeSH terms

  • Chromatography, Supercritical Fluid / methods*
  • Drug Discovery / methods*
  • High-Throughput Screening Assays
  • Linear Models
  • Mass Spectrometry
  • Pharmaceutical Preparations / analysis
  • Pharmaceutical Preparations / chemistry*
  • Reproducibility of Results
  • Stereoisomerism

Substances

  • Pharmaceutical Preparations