A 3D optical metamaterial made by self-assembly

Adv Mater. 2012 Mar 8;24(10):OP23-7. doi: 10.1002/adma.201103610. Epub 2011 Oct 24.

Abstract

Optical metamaterials have unusual optical characteristics that arise from their periodic nanostructure. Their manufacture requires the assembly of 3D architectures with structure control on the 10-nm length scale. Such a 3D optical metamaterial, based on the replication of a self-assembled block copolymer into gold, is demonstrated. The resulting gold replica has a feature size that is two orders of magnitude smaller than the wavelength of visible light. Its optical signature reveals an archetypal Pendry wire metamaterial with linear and circular dichroism.

Publication types

  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Butadienes / chemistry*
  • Gold / chemistry*
  • Models, Molecular
  • Molecular Conformation
  • Optical Phenomena*
  • Pentanes / chemistry*
  • Polystyrenes / chemistry*

Substances

  • Butadienes
  • Pentanes
  • Polystyrenes
  • polystyrene-block-polyisoprene
  • Gold