Interactions between colloids induced by a soft cross-linked polymer substrate

Phys Rev Lett. 2011 Sep 23;107(13):136101. doi: 10.1103/PhysRevLett.107.136101. Epub 2011 Sep 19.

Abstract

Using videomicroscopy imaging, we demonstrate the existence of a short-ranged equilibrium attraction between heavy silica colloids diffusing on soft surfaces of cross-linked polymer gels. The intercolloid potential can be tuned by changing the gel stiffness or by coating the colloids with a polymer layer. On sufficiently soft substrates, the interaction induced by the polymer matrix leads to large-scale colloidal aggregation. We correlate the in-plane interaction with a colloid-surface attraction.