Two-dimensional coalescence dynamics of encapsulated metallofullerenes in carbon nanotubes

ACS Nano. 2011 Dec 27;5(12):10084-9. doi: 10.1021/nn204003h. Epub 2011 Nov 9.

Abstract

We report on the coalescence of a two-dimensional (2D) chain of La@C(82) metallofullerene molecules encapsulated inside a single-wall carbon nanotube (SWNT). 2D packing of metallofullerenes is known to adopt a zigzag arrangement and cause elliptical distortion to the cross-section of the SWNT host. We show that after coalescence of the metallofullerenes into an inner nanotube the carbon nanotube host returns to its original circular cross-section. This is due to a relaxation of the strain caused by the packing of the encapsulated La@C(82) molecules into the nanotube. We identify the formation of some novel but transient fullerene-based structures formed during the intermediate stages of coalescence of the La@C(82) into an inner nanotube. These results highlight the flexible nature of SWNTs and their ability to adapt their cross-sectional profile depending upon forces induced by material encapsulated within.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Elastic Modulus
  • Fullerenes / chemistry*
  • Lanthanum / chemistry*
  • Macromolecular Substances / chemistry
  • Materials Testing
  • Metals / chemistry
  • Molecular Conformation
  • Nanotubes, Carbon / chemistry*
  • Nanotubes, Carbon / ultrastructure*
  • Particle Size
  • Surface Properties

Substances

  • Fullerenes
  • Macromolecular Substances
  • Metals
  • Nanotubes, Carbon
  • Lanthanum