Creation of stable molecular junctions with a custom-designed scanning tunneling microscope

Nanotechnology. 2011 Dec 2;22(48):485703. doi: 10.1088/0957-4484/22/48/485703. Epub 2011 Nov 9.

Abstract

The scanning tunneling microscope break junction (STMBJ) technique is a powerful approach for creating single-molecule junctions and studying electrical transport in them. However, junctions created using the STMBJ technique are usually mechanically stable for relatively short times (<1 s), impeding detailed studies of their charge transport characteristics. Here, we report a custom-designed scanning tunneling microscope that enables the creation of metal-single molecule-metal junctions that are mechanically stable for more than 1 minute at room temperature. This stability is achieved by a design that minimizes thermal drift as well as the effect of environmental perturbations. The utility of this instrument is demonstrated by performing transition voltage spectroscopy-at the single-molecule level-on Au-hexanedithiol-Au, Au-octanedithiol-Au and Au-decanedithiol-Au junctions.

Publication types

  • Research Support, U.S. Gov't, Non-P.H.S.