Four-stranded coiled-coil elastic protein in the byssus of the giant clam, Tridacna maxima

Biomacromolecules. 2012 Feb 13;13(2):332-41. doi: 10.1021/bm2013394. Epub 2012 Jan 5.

Abstract

An elastic protein with a secondary structure distinct from all well-known load-bearing proteins is found in the byssus of the giant clam, Tridacna maxima . The byssus consists of a bundle of hundreds of individual threads, each measuring about about 100 μm in diameter, which exhibit a tendon-like mechanical response. The amino acid composition of Tridacna byssus, however, is unlike tendon collagen, lacking high glycine, proline, and hydroxyproline. Wide-angle X-ray scattering (WAXS) and small-angle X-ray scattering (SAXS) measurements suggest that the constituent nanofibrils of the byssal threads are distinct from known secondary structure motifs previously reported for elastic proteins including the collagen triple-helix, the β-sheet nanocrystalline domains of silks, or the double-stranded coiled-coil regions of intermediate filaments. Instead, X-ray diffraction data indicate a structural organization in which four coiled-coil α-helices form a stable rope-like structure, which then further pack in a pseudohexagonal lattice to form nanofibrils. Amino acid composition analysis shows unusually high concentrations of acidic as well as basic residues, suggesting that the four-helix structure is stabilized by strong ionic interactions between oppositely charged residues in neighboring strands. The composition also suggests additional stabilization by disulfide cross-linking. On a larger scale, scanning and conventional transmission electron microscope (STEM and TEM) observations indicate that the nanofibrils exhibit an alternating periodicity of about 500 nm along the axial direction. A molecular model that combines the mechanical properties with the structural characteristics of the Tridacna byssal threads is proposed.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Amino Acids / analysis*
  • Animals
  • Bivalvia / chemistry
  • Bivalvia / physiology*
  • Crystallography, X-Ray
  • Disulfides / chemistry
  • Elasticity
  • Electrophoresis, Polyacrylamide Gel
  • Intermediate Filaments / chemistry
  • Intermediate Filaments / ultrastructure
  • Microscopy, Electron, Scanning
  • Models, Molecular
  • Nanofibers / chemistry*
  • Nanofibers / ultrastructure
  • Osmolar Concentration
  • Protein Structure, Secondary
  • Protein Structure, Tertiary
  • Proteins / chemistry*
  • Proteins / isolation & purification
  • Scattering, Small Angle
  • Weight-Bearing
  • X-Ray Diffraction

Substances

  • Amino Acids
  • Disulfides
  • Proteins