Phosphorylation-dependent activity of the deubiquitinase DUBA

Nat Struct Mol Biol. 2012 Jan 15;19(2):171-5. doi: 10.1038/nsmb.2206.

Abstract

Addition and removal of ubiquitin or ubiquitin chains to and from proteins is a tightly regulated process that contributes to cellular signaling and protein stability. Here we show that phosphorylation of the human deubiquitinase DUBA (OTUD5) at a single residue, Ser177, is both necessary and sufficient to activate the enzyme. The crystal structure of the ubiquitin aldehyde adduct of active DUBA reveals a marked cooperation between phosphorylation and substrate binding. An intricate web of interactions involving the phosphate and the C-terminal tail of ubiquitin cause DUBA to fold around its substrate, revealing why phosphorylation is essential for deubiquitinase activity. Phosphoactivation of DUBA represents an unprecedented mode of protease regulation and a clear link between two major cellular signal transduction systems: phosphorylation and ubiquitin modification.

Publication types

  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Crystallography, X-Ray
  • Endopeptidases / metabolism*
  • Humans
  • Models, Molecular
  • Phosphorylation
  • Protein Conformation
  • Protein Processing, Post-Translational*
  • Serine / metabolism*
  • Ubiquitin / metabolism

Substances

  • Ubiquitin
  • Serine
  • Endopeptidases
  • OTUD5 protein, human

Associated data

  • PDB/3TMO
  • PDB/3TMP