Simultaneous determination of lactate and pyruvate in human sweat using reversed-phase high-performance liquid chromatography: a noninvasive approach

Biomed Chromatogr. 2012 Nov;26(11):1408-15. doi: 10.1002/bmc.2713. Epub 2012 Feb 7.

Abstract

The simultaneous determination of lactate and pyruvate in sweat has been performed using reversed phase high-performance liquid chromatography (RP-HPLC) with UV detection at 220 nm. The calibration curves were linear in the investigated range 0.3 - 350 mm of lactate, 0.003- 1 mm of pyruvate. The sensitivity was good with a limit of detection of 0.03 mm for lactate and 0.001 mm for pyruvate. Recoveries evaluated for the entire procedure were 102 ± 0.1 and 96 ± 0.1 for lactate and pyruvate, respectively. The method was successfully applied to analysis of sweat in 8 athletes at rest (pilocarpine sweating) and during physical exercise.

MeSH terms

  • Adult
  • Chromatography, High Pressure Liquid / methods
  • Chromatography, Reverse-Phase / methods*
  • Exercise
  • Female
  • Humans
  • Lactic Acid / analysis*
  • Lactic Acid / metabolism
  • Linear Models
  • Male
  • Pyruvic Acid / analysis*
  • Pyruvic Acid / metabolism
  • Reproducibility of Results
  • Rest
  • Sensitivity and Specificity
  • Sweat / chemistry*
  • Sweat / metabolism

Substances

  • Lactic Acid
  • Pyruvic Acid