In situ electrokinetic enhancement for self-assembled-monolayer-based electrochemical biosensing

Anal Chem. 2012 Mar 20;84(6):2702-7. doi: 10.1021/ac203245j. Epub 2012 Mar 6.

Abstract

This study reports a multifunctional electrode approach which directly implements electrokinetic enhancement on a self-assembled-monolayer-based electrochemical sensor for point-of-care diagnostics. Using urinary tract infections as a model system, we demonstrate that electrokinetic enhancement, which involves in situ stirring and heating, can enhance the sensitivity of the strain specific 16S rRNA hybridization assay for 1 order of magnitude and accelerate the time-limiting incubation step with a 6-fold reduction in the incubation time. Since the same electrode platform is used for both electrochemical signal enhancement and electrochemical sensing, the multifunctional electrode approach provides a highly effective strategy toward fully integrated lab-on-a-chip systems for various biomedical applications.

Publication types

  • Evaluation Study
  • Research Support, N.I.H., Extramural
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Bacteria / genetics
  • Bacteria / isolation & purification*
  • Biosensing Techniques / instrumentation
  • Electrochemical Techniques / instrumentation*
  • Electrodes
  • Equipment Design
  • Escherichia coli / genetics
  • Escherichia coli / isolation & purification
  • Humans
  • Nucleic Acid Hybridization*
  • Pseudomonas aeruginosa / genetics
  • Pseudomonas aeruginosa / isolation & purification
  • RNA, Bacterial / genetics
  • RNA, Bacterial / urine*
  • RNA, Ribosomal, 16S / genetics
  • RNA, Ribosomal, 16S / urine*
  • Sensitivity and Specificity
  • Staphylococcus saprophyticus / genetics
  • Staphylococcus saprophyticus / isolation & purification
  • Urinary Tract Infections / diagnosis
  • Urinary Tract Infections / urine*

Substances

  • RNA, Bacterial
  • RNA, Ribosomal, 16S