Highly efficient synthesis of N-substituted isoindolinones and phthalazinones using Pt nanowires as catalysts

Org Lett. 2012 Apr 6;14(7):1876-9. doi: 10.1021/ol300471a. Epub 2012 Mar 15.

Abstract

A series of N-substituted isoindolinones have been successfully synthesized through the reductive C-N coupling and intramolecular amidation of 2-carboxybenzaldehyde and amines. This one-pot synthesis gives excellent yields using ultrathin Pt nanowires as catalysts under 1 bar of hydrogen. These unsupported catalysts can also be used for the synthesis of phthalazinones in high yield when hydrazine or phenyl hydrazine is used instead of amines.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Amines / chemistry
  • Catalysis
  • Isoindoles / chemical synthesis*
  • Isoindoles / chemistry
  • Molecular Structure
  • Nanowires / chemistry*
  • Phthalazines / chemical synthesis*
  • Phthalazines / chemistry
  • Platinum / chemistry*

Substances

  • Amines
  • Isoindoles
  • Phthalazines
  • Platinum