Emission analysis of RE3+ (RE = Sm, Dy):B2O3-TeO2-Li2O-AlF3 glasses

Luminescence. 2013 Mar-Apr;28(2):162-8. doi: 10.1002/bio.2356. Epub 2012 Mar 16.

Abstract

This article reports on the optical properties of 0.5% mol of Sm(3+), Dy(3+) ion-doped B2O3-TeO2-Li2O-AlF3 (LiAlFBT) glasses. The glass samples were characterized by optical absorption and emission spectra. Judd-Ofelt theory was applied to analyze the optical absorption spectra and calculate the intensity parameters and radiative properties of the emission transitions. The emission spectra of Sm(3+) and Dy(3+):LiAlFBT glasses showed a bright reddish-orange emission at 598 nm ((4)G5/2 → (6)H7/2) and an intense yellow emission at 574 nm ((4)F9/2 → (6)H13/2), respectively. Full width at half maximum (FWHM), stimulated emission cross section, gain bandwidth and optical gain values were also calculated to extend the applications of the Sm(3+) and Dy(3+):LiAlFBT glasses.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Aluminum Compounds / chemistry*
  • Boron Compounds / chemistry*
  • Dysprosium / chemistry*
  • Fluorides / chemistry*
  • Glass / chemistry*
  • Lithium / chemistry*
  • Polymers / chemical synthesis
  • Polymers / chemistry*
  • Samarium / chemistry*
  • Spectrum Analysis
  • Tellurium / chemistry*

Substances

  • Aluminum Compounds
  • Boron Compounds
  • Polymers
  • Dysprosium
  • tellurium dioxide
  • Samarium
  • boron oxide
  • Lithium
  • Tellurium
  • Fluorides
  • aluminum fluoride