Abstract
A Lewis acid (Ag(I), Ni(II), or Fe(II)) catalyzed, Cu(II)-mediated thiolation reaction between heteroarenes and thiols was achieved with good yield under base-free conditions. DMSO could serve as an effective methylthiolation reagent for the synthesis of heterocyclic methyl thioethers.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Catalysis
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Copper / chemistry*
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Heterocyclic Compounds / chemical synthesis*
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Heterocyclic Compounds / chemistry
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Lewis Acids / chemistry*
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Metals / chemistry*
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Molecular Structure
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Sulfides / chemical synthesis*
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Sulfides / chemistry
Substances
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Heterocyclic Compounds
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Lewis Acids
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Metals
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Sulfides
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Copper