Copper compound induces autophagy and apoptosis of glioma cells by reactive oxygen species and JNK activation

BMC Cancer. 2012 Apr 27:12:156. doi: 10.1186/1471-2407-12-156.

Abstract

Background: Glioblastoma multiforme (GBM) is the most aggressive of the primary brain tumors, with a grim prognosis despite intensive treatment. In the past decades, progress in research has not significantly increased overall survival rate.

Methods: The in vitro antineoplastic effect and mechanism of action of Casiopeina III-ia (Cas III-ia), a copper compound, on rat malignant glioma C6 cells was investigated.

Results: Cas III-ia significantly inhibited cell proliferation, inducing autophagy and apoptosis, which correlated with the formation of autophagic vacuoles, overexpression of LC3, Beclin 1, Atg 7, Bax and Bid proteins. A decrease was detected in the mitochondrial membrane potential and in the activity of caspase 3 and 8, together with the generation of intracellular reactive oxygen species (ROS) and increased activity of c-jun NH(2)-terminal kinase (JNK). The presence of 3-methyladenine (as selective autophagy inhibitor) increased the antineoplastic effect of Cas III-ia, while Z-VAD-FMK only showed partial protection from the antineoplastic effect induced by Cas III-ia, and ROS antioxidants (N-acetylcysteine) decreased apoptosis, autophagy and JNK activity. Moreover, the JNK -specific inhibitor SP600125 prevented Cas III-ia-induced cell death.

Conclusions: Our data suggest that Cas III-ia induces cell death by autophagy and apoptosis, in part due to the activation of ROS -dependent JNK signaling. These findings support further studies of Cas III-ia as candidate for treatment of human malignant glioma.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Antineoplastic Agents / pharmacology*
  • Apoptosis / drug effects*
  • Autophagy / drug effects
  • Catalase / metabolism
  • Cell Line, Tumor
  • Copper
  • Enzyme Activation / drug effects
  • Glioma / metabolism*
  • Humans
  • JNK Mitogen-Activated Protein Kinases / metabolism*
  • Organometallic Compounds / pharmacology*
  • Rats
  • Reactive Oxygen Species / metabolism*
  • Superoxide Dismutase / metabolism

Substances

  • (4,4-dimethyl-2,2-bipyridine)(acetylacetonate)copper(II)
  • Antineoplastic Agents
  • Organometallic Compounds
  • Reactive Oxygen Species
  • Copper
  • Catalase
  • Superoxide Dismutase
  • JNK Mitogen-Activated Protein Kinases