Sensitisation of the near-infrared emission of Nd(III) from the singlet state of porphyrins bearing four 8-hydroxyquinolinylamide chelates

Aurélie Guenet; Fabrice Eckes; Véronique Bulach; Cristian A Strassert; Luisa De Cola; Mir Wais Hosseini

doi:10.1002/cphc.201200328

Sensitisation of the near-infrared emission of Nd(III) from the singlet state of porphyrins bearing four 8-hydroxyquinolinylamide chelates

Chemphyschem. 2012 Sep 17;13(13):3163-71. doi: 10.1002/cphc.201200328. Epub 2012 Jul 16.

Authors

Aurélie Guenet¹, Fabrice Eckes, Véronique Bulach, Cristian A Strassert, Luisa De Cola, Mir Wais Hosseini

Affiliation

¹ Laboratoire de Chimie de Coordination Organique, UMR UdS-CNRS 7140, Institut Le Bel, Université de Strasbourg, 4 rue Blaise Pascal, CS 90032, 67081 Strasbourg Cedex, France.

PMID: 22807411
DOI: 10.1002/cphc.201200328

Abstract

The α(4) atropoisomer of a tetraaryl porphyrin and its Pd(II) complex, both bearing four hydroxyquinolinyl chelating units pre-organised on the same face of the porphyrin backbone, bind a Nd(III) centre thus affording either a mononuclear or a heterobinuclear anionic species, respectively. The near-infrared emission of the lanthanide centred at 1064 nm is observed upon excitation of the Soret band at 425 nm. Sensitisation proceeds mainly from the singlet state of the porphyrin.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Amides / chemistry
Chelating Agents / chemistry*
Coordination Complexes / chemistry
Hydroxyquinolines / chemistry*
Luminescence
Models, Molecular
Neodymium / chemistry*
Palladium / chemistry
Porphyrins / chemistry*
Spectrophotometry, Infrared

Substances

Amides
Chelating Agents
Coordination Complexes
Hydroxyquinolines
Porphyrins
Neodymium
Palladium