Direct spectroscopic evidence of CO spillover and subsequent reaction with preadsorbed NOx on Pd and K cosupported Mg-Al mixed oxides

Environ Sci Technol. 2012 Sep 4;46(17):9614-9. doi: 10.1021/es302018x. Epub 2012 Aug 21.

Abstract

The CO adsorption and subsequent reaction with preadsorbed NO(x) on Pd and K cosupported Mg-Al mixed oxides (Pd-K/MgAlO, 1/8/100 w/w) were investigated using in situ FTIR spectroscopy. During CO adsorption, a peculiar and well-defined IR band at 2160 cm(-1) was observed. Several elaborately designed experiments such as the competitive adsorption of CO and CO(2) demonstrated that the 2160 cm(-1) band was exclusively assigned to a carbonyl species on K sites due to the CO spillover from Pd to K, which results from a strong Pd-K interaction based on temperature-programmed reduction with H(2) experiments. Importantly, the spillover of CO is found to be involved in the reduction of preadsorbed NO(x) from temperature-programmed surface reactions with CO. Thus, all adsorbed NO(x) can be reduced by CO before desorption. Like the process of "pumping" CO by Pd from the atmosphere to "irrigate the field" of the nitrates/nitrites, the adsorbed NO(x) at not only K sites adjacent to Pd but also at the remote K sites can be reduced into N(2) and N(2)O effectively.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Adsorption
  • Aluminum Oxide / chemistry*
  • Carbon Monoxide / chemistry*
  • Magnesium Oxide / chemistry*
  • Nitric Oxide / chemistry*
  • Oxidation-Reduction
  • Palladium / chemistry*
  • Potassium / chemistry*
  • Spectroscopy, Fourier Transform Infrared

Substances

  • Nitric Oxide
  • Magnesium Oxide
  • Palladium
  • Carbon Monoxide
  • Aluminum Oxide
  • Potassium