High performance metal-organic-framework coatings obtained via thermal gradient synthesis

Chem Commun (Camb). 2012 Oct 9;48(78):9708-10. doi: 10.1039/c2cc34782b.

Abstract

For many possible applications of metal-organic frameworks, a coating onto a metallic support capable of both superior heat and mass transfer is required. A heated substrate in contact with a chilled solution of metal salt and linker reproducibly yields polycrystalline, highly stable, thermally conductive MOF coatings at a growth rate of 50 μm h(-1), illustrated by the formation of Cu(3)(btc)(2) as an example.