Histidine based fluorescence sensor detects Hg2+ in solution, paper strips, and in cells

Inorg Chem. 2012 Oct 1;51(19):10129-35. doi: 10.1021/ic300530f. Epub 2012 Sep 14.

Abstract

A chemosensor having a bipodal thiocarbamate scaffold attached to histidine moieties senses Hg(2+) with a remarkable selectivity. The binding results in a 50 nm blue shift in the fluorescence spectra and a 19-fold enhancement of the fluorescence quantum yield of the ligand. In addition to the detection of Hg(2+) visually under UV light in solution, the chemosensor was used for fabrication of paper strips that detected Hg(2+) in aqueous samples. The sensor was also used for imaging Hg(2+) in adult zebrafish and in human epithelial carcinoma HeLa S3 cells.

Publication types

  • Evaluation Study
  • Research Support, Non-U.S. Gov't

MeSH terms

  • Animals
  • Cations, Divalent / analysis
  • Fluorescent Dyes / chemistry*
  • HeLa Cells
  • Histidine / analogs & derivatives*
  • Humans
  • Mercury / analysis*
  • Microscopy, Fluorescence / methods
  • Paper
  • Sensitivity and Specificity
  • Spectrometry, Fluorescence / methods*
  • Water / analysis
  • Whole Body Imaging / methods
  • Zebrafish

Substances

  • Cations, Divalent
  • Fluorescent Dyes
  • Water
  • Histidine
  • Mercury