Optical absorption and near infrared emissions of Nd3+ doped fluorophosphate glass

Spectrochim Acta A Mol Biomol Spectrosc. 2012 Dec:98:355-8. doi: 10.1016/j.saa.2012.08.047. Epub 2012 Aug 26.

Abstract

Fluorophosphate glass doped with Nd(3+) has been synthesized with low OH content. Near infrared emissions centered around 0.9, 1.06, and 1.3 μm have been successfully obtained in present glass excited by a conventional 800 nm laser diode. Based on the absorption spectrum, radiative properties were calculated and discussed using the Judd-Ofelt theory. The luminescence characteristics and energy transfer mechanism were investigated. Desirable low OH(-) concentration and spectroscopic characteristics of Nd(3+)-doped fluorophosphate glass indicate that it is a promising material for near-infrared lasers.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Energy Transfer
  • Fluorides / chemical synthesis
  • Fluorides / chemistry*
  • Glass / chemistry*
  • Luminescence
  • Neodymium / chemistry*
  • Phosphates / chemical synthesis
  • Phosphates / chemistry*
  • Spectrometry, Fluorescence
  • Spectrophotometry
  • Spectroscopy, Near-Infrared

Substances

  • Phosphates
  • fluorophosphate
  • Neodymium
  • Fluorides