Abstract
This paper describes the design and synthesis of a new class of β-alanine derived dienes stabilized by Ni(II)-complex. Preliminary study of their Diels-Alder cycloaddition reactions with several types of dienophiles demonstrates their significant synthetic potential for the preparation of various polyfunctional β-aminocyclohexane carboxylic acids.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Amino Acids, Cyclic / chemical synthesis*
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Amino Acids, Cyclic / chemistry
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Catalysis
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Cycloaddition Reaction
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Cyclohexanecarboxylic Acids / chemical synthesis*
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Cyclohexanecarboxylic Acids / chemistry
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Molecular Structure
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Nickel / chemistry*
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beta-Alanine / chemistry*
Substances
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Amino Acids, Cyclic
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Cyclohexanecarboxylic Acids
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beta-Alanine
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Nickel