Rhodium-catalyzed regioselective amidation of indoles with sulfonyl azides via C-H bond activation

Org Biomol Chem. 2012 Dec 7;10(45):8953-5. doi: 10.1039/c2ob26767e. Epub 2012 Oct 18.

Abstract

Direct C-2 amidation of indoles was reported using sulfonyl azides as the amino source to release N(2) as the single byproduct. This reaction exhibits high functional group tolerance and regioselectivity, providing a variety of 2-amino substituted indoles in high to excellent yield. The procedure is robust, reliable, and compatible with water and air.

MeSH terms

  • Amides / chemistry*
  • Azides / chemistry*
  • Carbon / chemistry*
  • Catalysis
  • Hydrogen / chemistry*
  • Indoles / chemistry*
  • Rhodium / chemistry*
  • Stereoisomerism
  • Substrate Specificity

Substances

  • Amides
  • Azides
  • Indoles
  • Carbon
  • Hydrogen
  • Rhodium