High throughput paper spray mass spectrometry analysis

Clin Chim Acta. 2013 May:420:28-33. doi: 10.1016/j.cca.2012.10.025. Epub 2012 Oct 16.

Abstract

Background: Fast analysis of chemicals in samples of complex mixtures is important for many analytical applications including therapeutic drug monitoring and food safety screening.

Methods: Based on the paper spray technology developed recently, a high throughput device was developed in this work and used for evaluation of the fast quantitative analysis using paper spray mass spectrometry.

Results: The performance of the method was characterized with bovine blood samples spiked with sunitinib and nicotine. At optimized condition, relatively fast analysis speed of 7s/sample was achieved with relatively good LOQs (1 ng/ml) and quantitation.

Conclusion: In an application of the method for food screening, LODs better than 1 ng/g were achieved for clenbuterol in beef.

Publication types

  • Research Support, N.I.H., Extramural
  • Research Support, Non-U.S. Gov't
  • Research Support, U.S. Gov't, Non-P.H.S.

MeSH terms

  • Animals
  • Cattle
  • Chemistry Techniques, Analytical / methods*
  • Indoles / blood
  • Mass Spectrometry / instrumentation*
  • Nicotine / blood
  • Paper*
  • Pyrroles / blood
  • Sunitinib
  • Time Factors

Substances

  • Indoles
  • Pyrroles
  • Nicotine
  • Sunitinib