Synthesis of allenamides by Pd-catalyzed coupling of 3-alkoxycarbonyloxy ynamides or 1-alkoxycarbonyloxy allenamides with arylboronic acids

Org Biomol Chem. 2012 Dec 28;10(48):9556-61. doi: 10.1039/c2ob26727f. Epub 2012 Nov 1.

Abstract

An efficient palladium-catalyzed method is reported for the synthesis of multi-substituted allenamides by Suzuki-Miyaura cross-coupling reaction between easily prepared 3-alkoxycarbonyloxy ynamides or 1-alkoxycarbonyloxy allenamides and arylboronic acids.