Abstract
The heterometallic appended {MMn(III)(4)} (M = Dy(3+) and K(+)) cubanes were firstly trapped by two diamagnetic POM shells, which were robust enough to construct inorganic crystalline tubular materials. Magnetic study reveals the presence of a SMM-like slow magnetic relaxation feature in the heterometallic cluster-containing POM.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Capsules
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Dysprosium / chemistry*
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Ligands
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Manganese / chemistry*
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Models, Molecular
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Molecular Conformation
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Organometallic Compounds / chemistry*
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Potassium / chemistry*
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Tungsten Compounds / chemistry*
Substances
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Capsules
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Ligands
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Organometallic Compounds
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Tungsten Compounds
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Dysprosium
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Manganese
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Potassium
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tungstate