Abstract
A series of monoligated L·Pd(II)(Ar)X complexes (L = dialkyl biaryl phosphine) have been prepared and studied in an effort to better understand an unusual dearomative rearrangement previously documented in these systems. Experimental and theoretical evidence suggest a concerted process involving the unprecedented Pd(II)-mediated insertion of an aryl group into an unactivated arene.
Publication types
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Research Support, N.I.H., Extramural
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Research Support, Non-U.S. Gov't
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Research Support, U.S. Gov't, Non-P.H.S.
MeSH terms
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Coordination Complexes / chemistry
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Kinetics
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Ligands
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Magnetic Resonance Spectroscopy
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Models, Molecular
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Palladium / chemistry*
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Phosphines / chemistry*
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Thermodynamics
Substances
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Coordination Complexes
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Ligands
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Phosphines
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Palladium
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phosphine