Abstract
A noncentrosymmetric chiral Strandberg-type polyoxometalate based material, Cs(4)Mo(5)P(2)O(22), that contains unusual one dimensional chains constructed from [Mo(5)P(2)O(23)](6-) units has been reported. Cs(4)Mo(5)P(2)O(22) shows a moderate SHG response, and is phase-matchable.
Publication types
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Research Support, Non-U.S. Gov't
MeSH terms
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Cesium / chemistry*
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Molybdenum / chemistry*
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Oxides / chemistry*
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Polymerization
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Stereoisomerism
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Temperature
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Tungsten Compounds / chemistry*
Substances
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Oxides
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Tungsten Compounds
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polyoxometalate I
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Cesium
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Molybdenum