Are alkyne reductions chemo-, regio-, and stereoselective enough to provide pure (Z)-olefins in polyfunctionalized bioactive molecules?

Chem Rev. 2013 Mar 13;113(3):1313-50. doi: 10.1021/cr3001753. Epub 2012 Nov 29.
No abstract available

Publication types

  • Research Support, Non-U.S. Gov't
  • Review

MeSH terms

  • Alkenes / chemistry*
  • Alkynes / chemistry*
  • Boron Compounds / chemistry
  • Catalysis
  • Chemistry Techniques, Synthetic / methods*
  • Hydrogen
  • Hydrogenation
  • Oxidation-Reduction
  • Polyenes / chemical synthesis*
  • Rhodium / chemistry
  • Stereoisomerism
  • Structure-Activity Relationship
  • Titanium
  • Zinc / chemistry

Substances

  • Alkenes
  • Alkynes
  • Boron Compounds
  • Polyenes
  • Hydrogen
  • Titanium
  • Rhodium
  • Zinc