Abstract
High selectivity and low-energy regeneration for adsorption of CO(2) gas were achieved concurrently in a two-dimensional Cu(II) porous coordination polymer, [Cu(PF(6))(2)(4,4'-bpy)(2)](n) (4,4'-bpy = 4,4'-bipyridine), containing inorganic fluorinated PF(6)(-) anions that can act as moderate interaction sites for CO(2) molecules.
Publication types
-
Research Support, Non-U.S. Gov't
MeSH terms
-
Adsorption
-
Anions / chemistry
-
Carbon Dioxide / chemistry*
-
Copper / chemistry*
-
Crystallography, X-Ray
-
Hydrocarbons, Fluorinated / chemistry*
-
Models, Molecular
-
Organometallic Compounds / chemical synthesis
-
Organometallic Compounds / chemistry*
-
Polymers / chemistry*
-
Porosity
-
Surface Properties
Substances
-
Anions
-
Hydrocarbons, Fluorinated
-
Organometallic Compounds
-
Polymers
-
Carbon Dioxide
-
Copper