Rapid total synthesis of (±)trigonoliimine A via a Strecker/Houben-Hoesch sequence

Org Lett. 2013 Feb 1;15(3):528-30. doi: 10.1021/ol303344d. Epub 2013 Jan 11.

Abstract

A novel synthetic route to the hexacyclic system of trigonoliimine A was accomplished in four steps from N-phthaloyl 6-OMe-tryptamine. Key reactions include a three-component Strecker-type reaction to fashion the two C-N bonds in the D ring and a subsequent Houben-Hoesch type cyclization to deliver the characteristic seven-membered C ring.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Cyclization
  • Indole Alkaloids / chemical synthesis*
  • Indole Alkaloids / chemistry
  • Molecular Structure
  • Stereoisomerism

Substances

  • Indole Alkaloids
  • trigonoliimine A