Is the special pair structure a good strategy for the kinetics during the last step of the energy transfer with the nearest antenna? A chemical model approach

Jean-Michel Camus; Adam Langlois; Shawkat M Aly; Roger Guilard; Pierre D Harvey

doi:10.1039/c3cc38740b

Is the special pair structure a good strategy for the kinetics during the last step of the energy transfer with the nearest antenna? A chemical model approach

Chem Commun (Camb). 2013 Mar 18;49(22):2228-30. doi: 10.1039/c3cc38740b.

Authors

Jean-Michel Camus¹, Adam Langlois, Shawkat M Aly, Roger Guilard, Pierre D Harvey

Affiliation

¹ Institut de Chimie Moléculaire de l'Université de Bourgogne (ICMUB,UMR 6302), Université de Bourgogne, Dijon, France.

PMID: 23396549
DOI: 10.1039/c3cc38740b

Abstract

A cofacial bis(Mg(II)porphyrin)-C(6)H(4)-free base ([Mg(2)]-bridge-FB) dyad shows S(1) energy transfer in both directions and much slower rates than similar monoporphyrin systems are observed.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Energy Transfer
Kinetics
Magnesium / chemistry*
Metalloporphyrins / chemical synthesis
Metalloporphyrins / chemistry*
Models, Chemical*
Molecular Structure
Zinc / chemistry

Substances

Metalloporphyrins
Magnesium
Zinc