Calculations based on density functional theory show that the structure of Mn(4)Cl(9) anion is that of a Mn atom at the core surrounded by three MnCl(3) moieties. Since Mn is predominantly divalent and MnCl(3) is known to be a superhalogen with a vertical detachment energy (VDE) of 5.27 eV, Mn(4)Cl(9) can be viewed as a hyperhalogen with the formula unit Mn(MnCl(3))(3). Indeed, the calculated VDE of Mn(4)Cl(9) anion, namely 6.76 eV, is larger than that of MnCl(3) anion. More importantly, unlike previously discovered hyperhalogens, Mn(4)Cl(9) is the first such hyperhalogen species composed of only two constituent atoms. We further show that Mn(4)Cl(9) can be used as a ligand to design molecules with even higher VDEs. For example, Li[Mn(MnCl(3))(3)](2) anion has a VDE of 7.26 eV. These negatively charged clusters are antiferromagnetic with most of the magnetic moments localized at the Mn sites. Our studies show new pathways for creating binary hyperhalogens.