Titanium-catalyzed intermolecular hydroaminoalkylation of conjugated dienes

Till Preuss; Wolfgang Saak; Sven Doye

doi:10.1002/chem.201203693

Titanium-catalyzed intermolecular hydroaminoalkylation of conjugated dienes

Chemistry. 2013 Mar 18;19(12):3833-7. doi: 10.1002/chem.201203693. Epub 2013 Feb 20.

Authors

Till Preuss¹, Wolfgang Saak, Sven Doye

Affiliation

¹ Institut für Reine und Angewandte Chemie, Universität Oldenburg, Carl-von-Ossietzky-Strasse 9-11, 26111 Oldenburg, Germany.

PMID: 23426885
DOI: 10.1002/chem.201203693

Abstract

Ti me kangaroo down: Conjugated dienes undergo intermolecular hydroaminoalkylation in the presence of Ti catalyst [Ind2 TiMe2 ] (Ind=η(5) -indenyl). This new reaction offers a highly atom-efficient approach to homoallylic amines from 1,3-butadienes.