Jointly tuned plasmonic-excitonic photovoltaics using nanoshells

Nano Lett. 2013 Apr 10;13(4):1502-8. doi: 10.1021/nl304604y. Epub 2013 Mar 6.

Abstract

Recent advances in spectrally tuned, solution-processed plasmonic nanoparticles have provided unprecedented control over light's propagation and absorption via engineering at the nanoscale. Simultaneous parallel progress in colloidal quantum dot photovoltaics offers the potential for low-cost, large-area solar power; however, these devices suffer from poor quantum efficiency in the more weakly absorbed infrared portion of the sun's spectrum. Here, we report a plasmonic-excitonic solar cell that combines two classes of solution-processed infrared materials that we tune jointly. We show through experiment and theory that a plasmonic-excitonic design using gold nanoshells with optimized single particle scattering-to-absorption cross-section ratios leads to a strong enhancement in near-field absorption and a resultant 35% enhancement in photocurrent in the performance-limiting near-infrared spectral region.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Electric Power Supplies
  • Equipment Design
  • Gold / chemistry
  • Nanoshells / chemistry*
  • Quantum Dots / chemistry*
  • Solar Energy*

Substances

  • Gold