[(R)-2,2-Bis(diphenyl-phosphan-yl)-1,1'-binaphthyl-κ(2) P,P']{2-[(2R)-1,2-diamino-1-(4-meth-oxy-phen-yl)-3-methyl-but-yl]-5-meth-oxy-phenyl-κC (1)}hydrido-ruthenium(II) benzene monosolvate

Kamaluddin Abdur-Rashid; Alan J Lough

doi:10.1107/S1600536812046065

[(R)-2,2-Bis(diphenyl-phosphan-yl)-1,1'-binaphthyl-κ(2) P,P']{2-[(2R)-1,2-diamino-1-(4-meth-oxy-phen-yl)-3-methyl-but-yl]-5-meth-oxy-phenyl-κC (1)}hydrido-ruthenium(II) benzene monosolvate

Acta Crystallogr Sect E Struct Rep Online. 2012 Dec 1;68(Pt 12):m1486-7. doi: 10.1107/S1600536812046065. Epub 2012 Nov 17.

Authors

Kamaluddin Abdur-Rashid¹, Alan J Lough

Affiliation

¹ Kanata Chemical Technologies Inc., 101 College Street, Office 230, Toronto, Ontario, Canada M5G 1L7.

Abstract

In the title complex, [Ru(C19H25N2O2)H(C44H32P2)]·C6H6, the Ru(II) ion is in a distorted octa-hedral coordination environment with the hydride H atom trans to the tertiary carbinamine N atom, giving an H-Ru-N angle of 160.8 (12)°. The equatorial sites are occupied by two P atoms, the secondary carbinamine N atom and a coordinated C atom.