A platinum based organometallic turnstile

Chem Commun (Camb). 2013 May 7;49(35):3637-9. doi: 10.1039/c3cc41040d. Epub 2013 Mar 27.

Abstract

The synthesis of an organometallic turnstile based on a Pt(II) centre as a hinge was achieved. Its dynamic behaviour in solution was investigated using 1D and 2D NMR techniques. Using Ag(I) cation as an effector, the switching between its open and closed states in solution was demonstrated.