Metabolomic profiling reveals a role for caspase-2 in lipoapoptosis

J Biol Chem. 2013 May 17;288(20):14463-14475. doi: 10.1074/jbc.M112.437210. Epub 2013 Apr 3.

Abstract

The accumulation of long-chain fatty acids (LCFAs) in non-adipose tissues results in lipid-induced cytotoxicity (or lipoapoptosis). Lipoapoptosis has been proposed to play an important role in the pathogenesis of several metabolic diseases, including non-alcoholic fatty liver disease, diabetes mellitus, and cardiovascular disease. In this report, we demonstrate a novel role for caspase-2 as an initiator of lipoapoptosis. Using a metabolomics approach, we discovered that the activation of caspase-2, the initiator of apoptosis in Xenopus egg extracts, is associated with an accumulation of LCFA metabolites. Metabolic treatments that blocked the buildup of LCFAs potently inhibited caspase-2 activation, whereas adding back an LCFA in this scenario restored caspase activation. Extending these findings to mammalian cells, we show that caspase-2 was engaged and activated in response to treatment with the saturated LCFA palmitate. Down-regulation of caspase-2 significantly impaired cell death induced by saturated LCFAs, suggesting that caspase-2 plays a pivotal role in lipid-induced cytotoxicity. Together, these findings reveal a previously unknown role for caspase-2 as an initiator caspase in lipoapoptosis and suggest that caspase-2 may be an attractive therapeutic target for inhibiting pathological lipid-induced apoptosis.

Keywords: Apoptosis; Caspase; Hepatocyte; Lipids; Metabolism.

Publication types

  • Research Support, N.I.H., Extramural

MeSH terms

  • Aminooxyacetic Acid / metabolism
  • Animals
  • Apoptosis*
  • Carnitine / analogs & derivatives
  • Carnitine / metabolism
  • Caspase 2 / metabolism*
  • Cell Death
  • Chromatography, Gel
  • Enzyme Activation
  • Fatty Acids / metabolism*
  • Gene Expression Regulation, Enzymologic*
  • HEK293 Cells
  • Hepatocytes / cytology
  • Humans
  • Metabolomics / methods*
  • Palmitates / metabolism
  • RNA, Small Interfering / metabolism
  • Xenopus laevis / metabolism

Substances

  • Fatty Acids
  • Palmitates
  • RNA, Small Interfering
  • acylcarnitine
  • Aminooxyacetic Acid
  • Caspase 2
  • Carnitine