A facile strategy to Pt3Ni nanocrystals with highly porous features is developed. The integration of a high surface area and rich step/edge atoms endows the nanocrystals with an impressive oxygen reduction reaction (ORR) specific activity and mass activity. These nanocrystals are more stable in ORR and show a small activity change after 6000 potential sweeps. This is a promising material for practical electrocatalytic applications.
Keywords: Pt3Ni; alloys; oxygen reduction reaction; phenol; porous materials.
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