Toxicokinetics of α-thujone following intravenous and gavage administration of α-thujone or α- and β-thujone mixture in male and female F344/N rats and B6C3F1 mice

Toxicol Appl Pharmacol. 2013 Sep 1;271(2):216-28. doi: 10.1016/j.taap.2013.05.001. Epub 2013 May 10.

Abstract

Plants containing thujone have widespread use and hence have significant human exposure. α-Thujone caused seizures in rodents following gavage administration. We investigated the toxicokinetics of α-thujone in male and female F344/N rats and B6C3F1 mice following intravenous and gavage administration of α-thujone or a mixture of α- and β-thujone (which will be referred to as α,β-thujone). Absorption of α-thujone following gavage administration was rapid without any dose-, species-, sex- or test article-related effect. Absolute bioavailability of α-thujone following administration of α-thujone or α,β-thujone was generally higher in rats than in mice. In rats, females had higher bioavailability than males following administration of either test article although a sex difference was not observed in mice. Cmax and AUC∞ increased greater than proportional to the dose in female rats following administration of α-thujone and in male and female mice following administration of α,β-thujone suggesting possible saturation of elimination kinetics with increasing dose. Dose-adjusted AUC∞ for male and female rats was 5- to 15-fold and 3- to 24-fold higher than mice counterparts following administration of α-thujone and α,β-thujone, respectively (p-value<0.0001 for all comparisons). Following both intravenous and gavage administration, α-thujone was distributed to the brains of rats and mice with females, in general, having higher brain:plasma ratios than males. These data are in support of the observed toxicity of α-thujone and α,β-thujone where females were more sensitive than males of both species to α-thujone-induced neurotoxicity. In general there was no difference in toxicokinetics between test articles when normalized to α-thujone concentration.

Keywords: Bioavailability; Gavage; Neurotoxicity; Rodents; Thujone; Toxicokinetics.

Publication types

  • Research Support, N.I.H., Extramural

MeSH terms

  • Algorithms
  • Animals
  • Area Under Curve
  • Bicyclic Monoterpenes
  • Biological Availability
  • Brain Chemistry / drug effects
  • Chemistry, Pharmaceutical
  • Data Interpretation, Statistical
  • Female
  • Gas Chromatography-Mass Spectrometry
  • Half-Life
  • Injections, Intravenous
  • Intubation, Gastrointestinal
  • Isomerism
  • Male
  • Mice
  • Mice, Inbred Strains
  • Monoterpenes / administration & dosage
  • Monoterpenes / pharmacokinetics
  • Monoterpenes / toxicity*
  • Pharmacokinetics
  • Rats
  • Rats, Inbred F344

Substances

  • Bicyclic Monoterpenes
  • Monoterpenes
  • beta-thujone