Electrochemical route to fabricate film-like conjugated microporous polymers and application for organic electronics

Cheng Gu; Youchun Chen; Zhongbo Zhang; Shanfeng Xue; Shuheng Sun; Kai Zhang; Chengmei Zhong; Huanhuan Zhang; Yuyu Pan; Ying Lv; Yanqin Yang; Fenghong Li; Suobo Zhang; Fei Huang; Yuguang Ma

doi:10.1002/adma.201300839

Electrochemical route to fabricate film-like conjugated microporous polymers and application for organic electronics

Adv Mater. 2013 Jul 5;25(25):3443-8. doi: 10.1002/adma.201300839. Epub 2013 May 21.

Authors

Cheng Gu¹, Youchun Chen, Zhongbo Zhang, Shanfeng Xue, Shuheng Sun, Kai Zhang, Chengmei Zhong, Huanhuan Zhang, Yuyu Pan, Ying Lv, Yanqin Yang, Fenghong Li, Suobo Zhang, Fei Huang, Yuguang Ma

Affiliation

¹ State Key Laboratory of Supramolecular, Structure and Materials, Jilin University, Qianjin Avenue, Changchun 130012, P. R. China.

PMID: 23696222
DOI: 10.1002/adma.201300839

Abstract

Film-like conjugated microporous polymers (CMPs) are fabricated by the novel strategy of carbazole-based electropolymerization. The CMP film storing a mass of counterions acting as an anode interlayer provides a significant power-conversion efficiency of 7.56% in polymer solar cells and 20.7 cd A(-1) in polymer light-emitting diodes, demonstrating its universality and potential as an electrode interlayer in organic electronics.

Keywords: electrode interlayer; electropolymerization; film-like conjugated microporous polymers; ion store and release; organic electronics.

Publication types

Research Support, Non-U.S. Gov't