Determination of intestinal permeability of rigosertib (ON 01910.Na, Estybon): correlation with systemic exposure

J Pharm Pharmacol. 2013 Jul;65(7):960-9. doi: 10.1111/jphp.12057. Epub 2013 Mar 25.

Abstract

Objectives: Rigosertib (ON 01910.Na, Estybon) is a novel, anticancer agent undergoing phase 3 clinical trials for a lead indication against myelodysplastic syndromes (MDS). In this research, the permeability of rigosertib was evaluated using the in-situ perfused rat intestine (IPRI) model to support development of an oral formulation for rigosertib for treating cancer patients.

Methods: Experiments (n = 6 per group) were conducted using male Sprague-Dawley rats. Studies evaluated permeability across various intestinal segments and assessed the dose-linearity of absorption over the entire intestinal length. Drug concentrations in the portal and jugular vein were collected to correlate permeability parameters with presystemic and systemic exposure.

Key findings: Rigosertib permeability was highest in the jejunum, although parameter estimates indicated that rigosertib was a medium permeability compound. The compound displayed nonlinear absorption in the IPRI model, suggesting a saturable transport process. Transport inhibition studies using Caco-2 cells demonstrated that rigosertib was a P-glycoprotein (P-gp) substrate. Absolute bioavailability of rigosertib (10 and 20 mg/kg, 1-h infusion) in rats was estimated to be 10-15%. However, the fraction absorbed in humans predicted from IPRI data (52%) was consistent with published clinical data for rigosertib (35% oral bioavailability).

Conclusions: The results of this research indicated that rigosertib is a promising candidate for oral delivery. Further studies are needed to evaluate the potential impact of P-gp and other intestinal transporters on the oral absorption of this promising anticancer agent.

MeSH terms

  • ATP Binding Cassette Transporter, Subfamily B, Member 1 / metabolism
  • Administration, Oral
  • Animals
  • Antineoplastic Agents / administration & dosage
  • Antineoplastic Agents / pharmacokinetics*
  • Biological Availability
  • Biological Transport
  • Caco-2 Cells
  • Dose-Response Relationship, Drug
  • Drug Delivery Systems*
  • Glycine / administration & dosage
  • Glycine / analogs & derivatives*
  • Glycine / pharmacokinetics
  • Humans
  • Intestinal Absorption*
  • Intestinal Mucosa / metabolism
  • Male
  • Permeability
  • Rats
  • Rats, Sprague-Dawley
  • Sulfones / administration & dosage
  • Sulfones / pharmacokinetics*

Substances

  • ATP Binding Cassette Transporter, Subfamily B, Member 1
  • Antineoplastic Agents
  • Sulfones
  • ON 01910
  • Glycine