[Synthesis and acceptor properties of 11-[(9'-anthracenyl)methoxy]undecyl phosphate and P1-{11-[(9'-anthracenyl)methoxy]undecyl}-P2-(alpha-D-galactopyranosyl) diphosphate in the enzymic reactions catalyzed by galactosylphosphotransferase and mannosyltransferase from Salmonella newport]

Bioorg Khim. 2013 Jan-Feb;39(1):99-104. doi: 10.1134/s1068162013010123.
[Article in Russian]

Abstract

Fluorescent 11-[(9'-anthracenyl)methoxy]undecyl phosphate and P1-{11-[(9'-anthracenyl)methoxy]undecyl}-P2-(alpha-D-galactopyranosyl) diphosphate were chemically synthesized for the first time. The ability of the first compound to serve as substrate-acceptor ofgalactosyl phosphate residue and the second compound of mannosyl residue in enzymic reactions catalyzed by galactosylphosphotransferase and mannosyltransferase from Salmonella newport membrane preparation was demonstrated.

Publication types

  • English Abstract

MeSH terms

  • Galactosides / chemical synthesis*
  • Galactosides / chemistry
  • Galactosyltransferases / chemistry
  • Galactosyltransferases / metabolism
  • Mannosyltransferases / chemistry
  • Mannosyltransferases / metabolism*
  • Organophosphates / chemical synthesis*
  • Organophosphates / chemistry
  • Polyisoprenyl Phosphate Monosaccharides / chemical synthesis*
  • Polyisoprenyl Phosphate Monosaccharides / chemistry
  • Salmonella / enzymology*
  • Substrate Specificity

Substances

  • 11-((9'-anthracenyl)methoxy)undecylphosphate
  • Galactosides
  • Organophosphates
  • P1-(11-((9'-anthracenyl)methoxy)undecyl)-P2-(alpha-D-galactopyranosyl)diphosphate
  • Polyisoprenyl Phosphate Monosaccharides
  • polyprenyl phosphate-mannose
  • Galactosyltransferases
  • Mannosyltransferases